Read the following passage and answer the questions that follow : When metals are burnt in air, they form oxides. Metal oxides are generally basic in nature. But some metal oxides show both acidic as well as basic behaviour. Most metal oxides are insoluble in water, but some of these dissolve in water to form alkalis. Different metals show different reactivities towards oxygen. Metals such as sodium and potassium react vigorously whereas metals like silver and gold do not react with oxygen even at high temperature. (a) Why are metals like sodium and potassium kept immersed in kerosene oil ? (b) Why does copper metal turn black on heating? (c) (i) What are the amphoteric oxides ? Give two examples. OR (c) (ii) (I) Name a water soluble metal oxide. Write the chemical equation for its reaction with water. (II) Why do silver and gold not react with oxygen even at high temperature ?
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(a)Because of their high reactivity they react vigorously with air and water and catch fire if kept in open. (1 Mark) (b)Copper combines with oxygen to form $\ce{CuO}$ or Copper (II) Oxide, a black oxide/ $\ce{2Cu(s) + O2 -> 2CuO(s)}$ (1 Mark) (c) (i) Oxides which react with both acid and base to produce salt and water/ metal oxide which shows both acidic as well as basic behaviour. (1 Mark) Examples: $\ce{Al2O3}$, $\ce{ZnO}$ (½+½ Marks) (c) (ii) (I) • $\ce{Na2O/K2O/CaO}$/Sodium oxide /Potassium oxide/Calcium oxide (½ Mark) • $\ce{Na2O+H2O -> 2NaOH}$ / $\ce{K2O+H2O -> 2KOH}$ / $\ce{CaO+H2O -> Ca(OH)2}$ (1 Mark) (II) Because of the least reactive nature of silver and gold. (½ Mark)
(c) (ii) (I) Why highly reactive metals cannot be obtained from their oxides by using carbon as a reducing agent ? (II) Why solder, an alloy of lead and tin, is used for welding electrical wires together ?
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(a) Because it is easier to obtain metal from its oxide. / Because it is easier to reduce metal oxide to metal (1) (b) $\ce{Fe2O3(s)+ 2Al(s) -> 2Fe(l) + Al2O3(s) + Heat}$ $\ce{3MnO2(s) + 4Al(s) -> 3Mn(l) + 2Al2O3(s) + Heat}$ (1) (balancing is optional) (any one equation) (c) (i) $\ce{2Cu2S + 3O2(g) ->[Heat] 2Cu2O(s) + 2SO2 (g)}$ (1) $\ce{2Cu2O + Cu2S ->[Heat] 6Cu(s) + SO2(g)}$ (1) OR (c)(ii) (I) Because highly reactive metals have more affinity for oxygen than carbon. (1) (II) Because of its low melting point. (1)
Read the following passage and answer the questions that follow : One student was comparing the reactivity of different metals for his science project. He added iron filings in four test tubes A, B, C and D containing aqueous solutions of $\ce{ZnSO4}$, $\ce{CuSO4}$, $\ce{FeSO4}$ and $\ce{Al2(SO4)3}$. (i) In which of the test tubes will he observe the reaction to be the most vigorous and why ? (ii) Write a balanced equation for the reaction involved.
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(i) Test tube B Iron is more reactive than copper, so iron can displace copper from copper sulphate solution. (ii) $\ce{Fe(s) + CuSO4 (aq)->FeSO4 (aq)+Cu(s)}$
(b) Give reasons for the following : (i) Alloying is a very good method of improving the properties of a metal. (ii) Carbon cannot be used as a reducing agent to obtain highly reactive metals from their oxides. (iii) Silver articles become black after some time when exposed to air ?
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(b) (i) Alloying helps in getting desired properties in metals such as alloys are hard and strong, resistant to corrosion etc. (1 Mark) (3 Marks)
Comment on the following properties of ionic compounds and give reason in support of your answer : (i) Physical nature (ii) Melting and boiling points
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(i) Hard and brittle solid because of strong force of attraction between positive and negative ions. (ii) High melting and boiling point because a considerable amount of energy is required to break the strong inter-ionic attraction.
During the preparation of hydrogen chloride gas on a humid day, the gas is usually passed through a guard tube containing calcium chloride. The role of $\ce{CaCl2}$ taken in guard tube is to
Define ionic compound. Write two properties of ionic compounds.
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• The compound formed by transfer of electrons from metal to non-metal. (1 Mark) Properties: • Generally soluble in water, ($\frac{1}{2}$ Mark) • high melting point and boiling point, ($\frac{1}{2}$ Mark) • good conductor of heat and electricity. ($\frac{1}{2}$ Mark) (any two or any other) (2 Marks)
(i) Give reasons for the following : (I) Ionic compound have generally high melting points and boiling points. (II) Solder, an alloy of lead and tin, is used for welding electrical wires. (III) Carbon cannot reduce the oxides of $\ce{Na}$ or $\ce{Mg}$. (ii) The reaction of compound ‘X’ with aluminium is used to join railway tracks : (I) Identify the compound ‘X’. (II) Name the reaction. (III) Write the balanced chemical equation of the reaction of compound ‘X’ with aluminium.
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(i) (I) A considerable amount of energy is required to break strong inter-ionic attraction. (1 Mark) (II) Solder has low melting point. (1 Mark) (III) Because Na or Mg have more affinity for oxygen than carbon. (1 Mark) (ii) (I) $\ce{Fe2O3}$/ Iron (III) oxide (½ Mark) (II) Thermit reaction (½ Mark) (III) $\ce{Fe2O3(s) + 2Al(s) -> 2Fe(l) + Al2O3(s) + Heat}$ (1 Mark) (Deduct ½ mark if no/ incorrect balancing)
Read the following passage and answer the questions given below : Most of metals occur in combined state in form of ores. Carbonate ores are converted into oxides by calcination and sulphide ores by roasting. Oxides are reduced with suitable reducing agent like carbon to get free metal. Highly reactive metals like – $\ce{Al}$, $\ce{Mg}$ are also used as reducing agents to obtain metal from their oxides. Most reactive metals are obtained by electrolytic reduction of their molten ores. Alloying is a very good method of improving the properties of a metal. We can get desired properties by this method. The electrical conductivity and melting point of an alloy is less than that of pure metals. (a) Why carbonate or sulphide ores are converted to oxides before extraction of metal from it? (b) Write a reaction in which Aluminium is used as a reducing agent to obtain metal from its oxide.
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(a) Because it is easier to obtain metal from its oxide. / Because it is easier to reduce metal oxide to metal (1) (b) $\ce{Fe2O3(s)+ 2Al(s) -> 2Fe(l) + Al2O3(s) + Heat}$ $\ce{3MnO2(s) + 4Al(s) -> 3Mn(l) + 2Al2O3(s) + Heat}$ (1) (balancing is optional) (any one equation) (c) (i) $\ce{2Cu2S + 3O2(g) ->[Heat] 2Cu2O(s) + 2SO2 (g)}$ (1) $\ce{2Cu2O + Cu2S ->[Heat] 6Cu(s) + SO2(g)}$ (1) OR (c)(ii) (I) Because highly reactive metals have more affinity for oxygen than carbon. (1) (II) Because of its low melting point. (1)
(c) (i) How is copper obtained from its ore ($\ce{Cu2S}$) ? Give equations of the reactions.
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(a) Because it is easier to obtain metal from its oxide. / Because it is easier to reduce metal oxide to metal (1) (b) $\ce{Fe2O3(s)+ 2Al(s) -> 2Fe(l) + Al2O3(s) + Heat}$ $\ce{3MnO2(s) + 4Al(s) -> 3Mn(l) + 2Al2O3(s) + Heat}$ (1) (balancing is optional) (any one equation) (c) (i) $\ce{2Cu2S + 3O2(g) ->[Heat] 2Cu2O(s) + 2SO2 (g)}$ (1) $\ce{2Cu2O + Cu2S ->[Heat] 6Cu(s) + SO2(g)}$ (1) OR (c)(ii) (I) Because highly reactive metals have more affinity for oxygen than carbon. (1) (II) Because of its low melting point. (1)
The slow and gradual degradation of metals due to their reaction with moisture, acids etc. present in the atmosphere is called corrosion. (1 Mark) Silver articles react with sulphur in the air to form a coating of silver sulphide, which is black in colour. (1 Mark) A – Carbon dioxide/ $\ce{CO2}$ (1 Mark) Green coating is of copper carbonate/ $\ce{CuCO3}$ (1 Mark) OR An alloy is a homogenous mixture of two or more metals, or a metal and a non-metal. (1 Mark) It is made by mixing the metals in molten state. (1 Mark)
OR (b) Give reasons : (i) Metal sulphides and carbonates should be converted to their metal oxides in the process of extraction of metals. (ii) Aluminium oxide is considered as an amphoteric oxide. (iii) Metals like $\ce{Na}$, $\ce{K}$, $\ce{Ca}$ and $\ce{Mg}$ are never found in their free state in nature.
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(b) (i) It is easier to obtain metal from its metal oxide / It is easier to reduce metal oxide to metal. (ii) Aluminium Oxide can react with both acids as well as bases to form salt and water. $\ce{Al2O3 + 6HCl -> 2AlCl3 + 3H2O}$ $\ce{Al2O3 + 2NaOH -> 2NaAlO2 + H2O}$ (iii)As they are highly reactive metals so exist in combined state.
(i) Which method will be used to convert each of them to their respective metal oxides ? (a) Carbonate ore (b) Sulphide ore (ii) Write a chemical reaction to illustrate the use of aluminium for joining cracked railway tracks. (iii) During extraction of metals, electrolytic refining is used to obtain pure metals. Which material will be used as anode and cathode for the refining of copper metal by this process ?
(i) Write all the reactions involved in the extraction of $\ce{Zn}$ from $\ce{ZnS}$. (ii) Hydrogen gas is not evolved when most of the metals react with nitric acid. Give reason.
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(i) $\ce{2ZnS(s) + 3O2(g) ->[Heat] 2ZnO(s) + 2SO2(g)}$ (1 Mark) $\ce{ZnO(s) + C(s) -> Zn(s) + CO(g)}$ (1 Mark) (ii) Nitric acid is a strong oxidising agent and oxidises $\ce{H2}$ gas produced to water. (1 Mark)
(a) Define the following terms with an example : (i) Roasting (ii) Alloy (iii) Corrosion
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(a) (i) The conversion of sulphide ore into oxide by heating strongly in the presence of excess air. ($\frac{1}{2}$ Mark) $\ce{2ZnS(s) + 3O2(g) ->[Heat] 2ZnO(s) + 2SO2(g)}$ ($\frac{1}{2}$ Mark) (Or any other example) (ii) • An alloy is a homogeneous mixture of two or more metals or a metal and a non-metal. ($\frac{1}{2}$ Mark) • Example Brass ($\frac{1}{2}$ Mark) (or any other) (iii) The slow and gradual degradation of metals due to their reaction with moisture, acids etc. present in the atmosphere is called corrosion ($\frac{1}{2}$ Mark) Example: Formation of $\ce{Fe2O3.xH2O}$ (Rust) or silver sulphide on silver articles. ($\frac{1}{2}$ Mark) (any one or any other) (3 Marks)
Attempt either (a) or (b) : (a) (i) Write the balanced chemical equation involved in the extraction of : (I) $\ce{Hg}$ from $\ce{HgS}$ (II) $\ce{Zn}$ from $\ce{ZnCO3}$ (III) $\ce{Na}$ from $\ce{NaCl}$ (ii) Why does sodium chloride : (I) not conduct electricity in solid state ? (II) have very high melting point ?
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(a) (i) (I) $\ce{2HgS(s) + 3O2(g) ->[Heat] 2HgO(s) + 2SO2(g)}$ $\ce{2HgO(s) ->[Heat] 2Hg(l) + O2(g)}$ (1) (II) $\ce{ZnCO3(s) ->[Heat] ZnO(s) + CO2(g)}$ $\ce{ZnO(s) + C(s) -> Zn(s) + CO(g)}$ (1) (III) At cathode $\ce{Na+ + e- -> Na}$ At anode $\ce{2Cl- -> Cl2 + 2e-}$ (1) (ii) (I) Because movement of ions in solid state is not possible due to its rigid structure. (1) (II) A large amount of heat energy is required to overcome strong electrostatic forces of attraction between oppositely charged ions in ionic compounds. (1) OR (b) (i) $\bullet$ Cathode – Thin strip of pure zinc metal ($\frac{1}{2}$) $\bullet$ Anode – Impure zinc metal ($\frac{1}{2}$) (ii) $\bullet$ A solution of Zinc salt like $\ce{ZnSO4}$. (1) $\bullet$ On the cathode. (1) (iii) $\bullet$ Zinc forms a protective layer on iron preventing reaction of air and water with iron surface. (1) $\bullet$ Galvanisation. (1)
(b) During extraction of metals, electrolytic refining is used to obtain pure metals. (i) Which material will be used as cathode and anode for refining of zinc metal by this process ? (ii) Name the electrolyte used in this process. Where do we get pure zinc after passing electric current ? (iii) How does zinc prevent rusting of iron ? Also, name the process.
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(a) (i) (I) $\ce{2HgS(s) + 3O2(g) ->[Heat] 2HgO(s) + 2SO2(g)}$ $\ce{2HgO(s) ->[Heat] 2Hg(l) + O2(g)}$ (1) (II) $\ce{ZnCO3(s) ->[Heat] ZnO(s) + CO2(g)}$ $\ce{ZnO(s) + C(s) -> Zn(s) + CO(g)}$ (1) (III) At cathode $\ce{Na+ + e- -> Na}$ At anode $\ce{2Cl- -> Cl2 + 2e-}$ (1) (ii) (I) Because movement of ions in solid state is not possible due to its rigid structure. (1) (II) A large amount of heat energy is required to overcome strong electrostatic forces of attraction between oppositely charged ions in ionic compounds. (1) OR (b) (i) $\bullet$ Cathode – Thin strip of pure zinc metal ($\frac{1}{2}$) $\bullet$ Anode – Impure zinc metal ($\frac{1}{2}$) (ii) $\bullet$ A solution of Zinc salt like $\ce{ZnSO4}$. (1) $\bullet$ On the cathode. (1) (iii) $\bullet$ Zinc forms a protective layer on iron preventing reaction of air and water with iron surface. (1) $\bullet$ Galvanisation. (1)
A student notices that her silver jewellery turned dull and had a grey-black coating over it after wearing for a few months. What results in the change in colour of the silver metal ?
(a)The polish over the jewellery was removed after wearing for a few months.
(b)The jewellery comes in contact with air, moisture and acids and corrodes.
(c)Dust particles over the jewellery change its colour.
(d)Its colour changes due to rusting.
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(B) / The jewellery comes in contact with air, moisture and acids and corrodes. (1 Mark)
Galvanization is a process of coating iron articles with a thin layer of zinc to prevent iron from rusting. The iron is protected even if the zinc coating is scratched and iron is exposed. Which of the following is/are true about how zinc prevents the rusting of iron ? (P) A galvanised iron article does not undergo oxidation. (Q) The zinc coating prevents contact of iron with air. (R) Zinc provides continuous protection to iron from rusting.
The Statue of Liberty is one of the seven wonders. It is present on Liberty island in New York harbour in U.S.A. It is made up of a metal. Over a period of time, the metal's colour has changed and statue gives greenish look. Answer the following questions based on the above information : (A) What is corrosion ? (B) Why do silver articles turn black after some time?
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The slow and gradual degradation of metals due to their reaction with moisture, acids etc. present in the atmosphere is called corrosion. (1 Mark) Silver articles react with sulphur in the air to form a coating of silver sulphide, which is black in colour. (1 Mark) A – Carbon dioxide/ $\ce{CO2}$ (1 Mark) Green coating is of copper carbonate/ $\ce{CuCO3}$ (1 Mark) OR An alloy is a homogenous mixture of two or more metals, or a metal and a non-metal. (1 Mark) It is made by mixing the metals in molten state. (1 Mark)
The Statue of Liberty is one of the seven wonders. It is present on Liberty island in New York harbour in U.S.A. It is made up of a metal. Over a period of time, the metal's colour has changed and statue gives greenish look. Answer the following questions based on the above information : (A) What is corrosion ? (B) Why do silver articles turn black after some time? (C) Copper reacts with moist gas 'A' present in the air and slowly loses its shiny surface. It turns green. Identify 'A' and the substance of green coating formed on the surface of copper.
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The slow and gradual degradation of metals due to their reaction with moisture, acids etc. present in the atmosphere is called corrosion. (1 Mark)
Copper reacts with moist gas 'A' present in the air and slowly loses its shiny surface. It turns green. Identify 'A' and the substance of green coating formed on the surface of copper.
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The slow and gradual degradation of metals due to their reaction with moisture, acids etc. present in the atmosphere is called corrosion. (1 Mark) Silver articles react with sulphur in the air to form a coating of silver sulphide, which is black in colour. (1 Mark) A – Carbon dioxide/ $\ce{CO2}$ (1 Mark) Green coating is of copper carbonate/ $\ce{CuCO3}$ (1 Mark) OR An alloy is a homogenous mixture of two or more metals, or a metal and a non-metal. (1 Mark) It is made by mixing the metals in molten state. (1 Mark)